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Metal-ion-catalyzed σ-bond rearrangement
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Metal-ion-catalyzed σ-bond rearrangement : ウィキペディア英語版
Metal-ion-catalyzed σ-bond rearrangement
The metal-ion-catalyzed σ-bond rearrangement reaction occurs with highly saturated organic ring molecules treated by Ag+, Rh(I), or Pd(II) ions.〔Michael B. Smith, Jerry March, March's Advanced Organic Chemistry, 5th Ed., John Wiley & Sons, Inc., 2001, p. 1459. ISBN 0-471-58589-0〕 Two types of the reaction were noted: () ring openings, and a conversion to another ring system:
:
A mechanism for this rearrangement reaction is not completely understood, however some explanations were suggested.
== See also ==

* Cyclobutane
* Cubane
* Cuneane

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